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What is Portland Cement?
It is the generic term for fine, gray or white
powder manufactured using high temperature to produce calcium silicates
that, in the presence of water, will undergo hydration producing
a product that will bring aggregates together to produce mortar,
stucco or concrete.
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Why
is it called Portland cement? Joseph Aspdin, an English
mason who patented the product in 1824, named it portland cement
because it produced a concrete that resembled the color of the natural
limestone quarried on the Isle of Portland, a peninsula in the English
Channel.
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How is Portland cement
made? Portland cement is made when materials
that contain proper amounts of calcium compounds, silica, alumina
and iron oxide are crushed and screened and placed in a rotating
cement kiln. Ingredients used in this process are usually materials
such as limestone, marl, shale, iron, ore, clay, and fly ash.
The kiln or the furnace resembles a large horizontal pipe with a
diameter of 10 to 15 feet (3 to 4.1 meters) and a length of 300
feet (90 meters) or more. One end is raised slightly. The raw mix
is placed in the high end and as the kiln rotates the materials
moves slowly toward the lower end. Flame jets are located at the
lower end. All the materials in the kiln are heated to high temperatures
that range between 2700 and 3000 Fahrenheit (1480 and 1650 Celsius).
This high heat drives off, or calcines, the chemically combined
water and carbon dioxide from the raw materials and forms new compounds
(tricalcium silicate, dicalcium silicate, tricalcium aluminate and
tetracalcium aluminoferrite). For every ton of material that goes
into the feed end of the kiln, two thirds of a ton that comes out
the discharge end, called clinker. The clinker is in the shape and
appearance of marble sized pellets. The clinker is very finely ground
to produce Portland cement. To control the cement’s rate of
hardening, a small amount of gypsum is added during the grinding
process.
Click this button to launch the Cement Making Process Virtual Tour.
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What are the different
kinds of cement? Portland cement and blended
cement.
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Are there different types
of Portland cement? All Portland cement
is mainly similar but there are eight types of cement that are manufactured
to meet various physical and chemical requirements for specific
applications:
- Type I is a general purpose Portland cement
that is suitable for most uses.
- Type II is used for constructions in water
or soil that contains moderate amounts of sulphate, or when heat
build-up is a concern.
- Type III cement provides and supplies high
strength at an early state, usually in a week or less.
- Type IV moderates heat produced by hydration
that is used for massive concrete surfaces such as dams.
- Type V cement resists chemical attack by soil
and water high in sulfates.
- Type IA, IIA and IIIA are cements used to
make air-entrained concrete. They have the same properties as
types I, II, and III, but with the exception of possessing small
quantities of air-entrained materials shared and combined with
them.
White Portland cement is made from raw materials
which contain little or no iron or manganese. These are the substances
that give conventional cement its gray color.
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What is blended cement?
Blended hydraulic cements are produced
by intimately and uniformly intergrinding or blending two or more
types of fine materials. The primary materials are portland cement,
ground granulated blast furnace slag, fly ash, silica fume, calcined
clay, other pozzolans, hydrated lime, and pre-blended combinations
of these materials.
What are the types of blended cement?
Type IS-Portland blast furnace slag cement
Type IP and Type P-Portland-pozzolan cement
Type I(PM)-Pozzolan-modified portland cement
Type S-Slag cement
Type I(SM)-Slag-modified portland cement.
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What are the raw materials
used in the manufacturers of Portland cement? The
two main raw materials used in making Portland cement are calcareous
substances like chalk, limestone, marl or shells and argillaceous
elements like clay and shale that are rich in silica.
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What is the difference
between cement and concrete? Cement is
actually an ingredient of concrete. Concrete is a mixture of aggregates
and paste. The aggregates are sand and gravel or crushed stone;
the paste is water and Portland cement. Concrete is a hard, strong
construction material consisting of sand, conglomerate gravel, pebbles,
broken stone, or slag in a mortar or cement matrix. Concrete gets
stronger as it gets older. Portland cement is the generic for the
type of cement used in virtually all concrete. Cement compromises
from 10 to 15 percent of the concrete mix, by volume. In the process
called hydration, the cement and water harden and bind the aggregates
into a rocklike mass. This hardening process continues for years
that it brings the idea that concrete gets stronger and tougher
as it gets older.
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What does it mean to “cure”
concrete? Curing is a very important step
in concrete construction. When concrete has been cured properly,
it greatly increases its strength and durability. Through the result
of hydration, concrete hardens. It is the chemical reaction between
cement and water. Hydration occurs only if water is available and
if the concrete’s temperature stays within a suitable range.
During the curing period which is from five to seven days after
the placement for conventional concrete, the concrete surface needs
to be kept moist to allow the hydration process. The new concrete
can be wet with soaking hoses, sprinklers or covered with wet burlap,
or can be coated with commercially available curing compounds, which
seal in moisture.
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Why is gypsum needed
in cement? Gypsum plays a very important
role in controlling the rate of which hardening of the cement develops.
It must be controlled within the limits to make the cement a useful
product in construction. Small amount of gypsum are added to the
clinkers at the grounding period.
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Will cement harden in
water? Portland cement is hydraulic cement.
It means that it sets and hardens due to a chemical reaction with
water.
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What causes hardening
in Portland cement? The compounds present
in Portland cement react with water to form a cementitious crystalline
structure that adheres to the sand and aggregate. This helps in
binding the mass together and increases its strength till it becomes
very hard.
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What does 28-day strength
mean? When concrete hydrates, it hardens
and gains strength. This hydration process continues over a long
period of time. It occurs quickly at the outset and slows down as
time passes. It would require a wait of several years before the
strength of concrete can really be measured. Since this is impractical,
a time period of 28 days was introduced by specification-writing
authorities as the time where all concrete should be tested. In
this period, a substantial percentage of the hydration has already
taken place.
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How do you control the strength
of concrete?
In order to add strength to concrete, one has
to add cement. The ratio of water to cement in the paste that binds
the aggregates together plays a big role in controlling the strength
of concrete. The higher the ratio, the weaker the concrete will
be and vice versa. Every desirable physical property that you can
measure will be adversely affected by adding more water.
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Is there a universal
international specification for Portland cement? No.
There is no universal international standard for Portland cement
because every country has their own standard. The United States
uses the specification prepared by the American Society for Testing
and Material (ASTM C-150) Standard Specification for Portland cement.
A few other countries have also adopted this, however, there are
countless other conditions. Unfortunately, they do not use the same
criteria for measuring properties and defining physical characteristics
so they can be virtually “non-translatable.” The European
Cement Association located in Brussels, Belgium, publishes a book
entitled “Cement Standards of the World.”
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What is setting of cement?
When water is mixed with cement, a smooth paste
is produced that remains plastic for a short time. During this period,
the paste can be disturbed and remixed without injury. As the reaction
between water and cement continues, the plasticity of the cement
paste is lost. This early period in the hardening of cement is known
as `Setting of Cement'.
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What is Heat of Hydration
and its significance? Hardening of cement
is caused by some reactions described by the process of liberation
of heat. This is referred to as Heat of Hydration. In mass concreting
jobs like dams where dissipation of heat is not possible, the temperature
of concrete rises. On subsequent cooling, cracks develop. Hence,
it is very necessary to use cement with low heat of hydration in
massive structures.
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Can cement irritate my
hands? There are some people who are more
sensitive to the free lime than other people. It may cause some
irritations if it comes in contact with the eyes. It also possible
that cracked skin will leave you more susceptible to dermatitis.
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